#colligative

Getzler Lab at KenyonCollegeGetzlerChem@mstdn.science
2024-06-17

Interesting article questioning the longstanding and widely accepted theory that the molecular weight dependence of glass transition in linear #polymers is essentially a #colligative property driven by dilution of chain ends. Odd that they do not examine data on #cyclic polymers. I know Grubbs cyclooctene REP achieved very high MW. #chemistry doi.org/10.1021/acs.macromol.4c00419

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